The definitive answer is no. Unlocking an iPhone does not trigger a notification or any discernible event on the paired Apple Watch. This behavior is by design, stemming from security considerations and the intended functional separation between the two devices.. The notification will go to the "active" device, meaning notification will go to the watch if it's unlocked and you're wearing it. The notification will go to the phone if you're actively using the phone.
How to get notifications on your iPhone and Apple Watch If you don't get notifications in the way that you want or expect, you might need to check your settings or a paired device, like an Apple Watch.. However, while that allows you to unlock an iPhone whilst wearing a mask, this is about the Apple Watch being unlocked. This new notification appears both when the passcode is entered.