Libby Rios, left, wife of former Columbia Police Officer Steven Rios

The jurors thought he made a pit stop on Wilson. At 5:15 a.m., Libby Rios Sullivan awoke to the sound of her son squealing on the baby monitor.. According to Dateline, Steven Arthur Rios served at the Columbia Police Department for a long time and was married to a woman named Libby Sullivan during the time of Jesse Valencia's murder. Rios and Sullivan even had their first child the same year the incident took place. However, things went awry when Rios came across Valencia while raiding a party of youngsters. According to reports, Jesse.

Libby Sullivan is Focusing on Her Family Today From what we can tell, despite Libby's testimony in Steven's favor during his 2005 murder trial, her continued trust in his innocence, as well as her love for him, she filed to end their marriage following his conviction.. Steven Arthur Rios was a long-serving officer with the Columbia, Missouri, Police Department. In 2004, the 27-year-old was married to Libby Sullivan, his college sweetheart, and the couple had welcomed their first son earlier that year.